Super-Stretchy Hydrogel Can Take a Hit

A polymer network made of alginate and polyacrylamide is the most resilient yet and could be used in replacement cartilage or scaffolding for artificial organs

By Katharine Sanderson and Nature magazine

From Nature magazine

Your eyes aren?t deceiving you ? you just watched a metal ball bounce off a sliver of jelly. But you wouldn?t put this jelly in a sherry trifle: it is a sophisticated hydrogel developed by Zhigang Suo, a materials engineer at Harvard University in Cambridge, Massachusetts, and his colleagues¹.

A hydrogel is a network of polymers that soaks up lots of water to form a jelly-like material. But most shatter easily and don?t stretch far without breaking. Some of the toughest hydrogels are used to make soft contact lenses, and researchers want to make them more robust, for use in replacement cartilage or as scaffolds for growing artificial organs.

Suo?s hydrogel is made from a mixture of two polymers ? alginate and polyacrylamide. Each polymer forms networks using different types of chemical bond: alginate molecules are linked together by ionic bonds, and polyacrylamide molecules by stronger covalent bonds. When the gel is stretched, hit or torn, the ionic bonds can break and reform throughout the material, dissipating energy over a wide area and causing fewer of the covalent bonds to be irreversibly ruptured. The covalent bonds hold the material together, allowing it to spring back to its original shape.

Separately, the two polymers can each form normal hydrogels ? but when they are mixed together, the resulting material is far stronger than its constituent parts. The energy needed to fracture the combination hydrogel is on a par with that for natural rubber at 9,000 joules per square metre, and the gel can be stretched to 20 times its original length without breaking. ?You can?t even tear it apart with your hands,? says Suo.

This article is reproduced with permission from the magazine Nature. The article was first published on September 5, 2012.

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